Half-upright position. Detia Degesch GmbH – Ihr internationaler Partner in Sachen Vorratsschutz, Begasungen, Ratten- und Mäusebekämpfung, Insektizide, Monitoring und andere Schädlingsbekämpfungsmittel Do not discharge to sewer systems. Aluminum phosphate 99.99% trace metals basis; CAS Number: 7784-30-7; EC Number: 232-056-9; Linear Formula: AlO4P; find Sigma-Aldrich-255963 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. Details of the supplier of the safety data sheet Emergency Telephone … If material on fire or involved in fire: Do not use water. Aluminium phosphate is a chemical compound. This colourless solid is generally sold as a grey-green-yellow powder due to the presence of impurities arising hydrolysis and oxidation . Substance Data Source: TOXNET. Aluminiumphosphid kann durch Zusammenschmelzen von rotem Phosphor mit Aluminium gewonnen werden: + Alternativ kann ein äquimolares Gemisch von rotem Phosphor und Aluminium mittels Magnesiumband entzündet werden. Wash and dry hands. They have framework structures similar to zeolites and some are used as catalysts, ion-exchangers or molecular sieves. Then store and dispose of according to local regulations. Aluminum phosphide is not flammable by itself. /K -1 /Columns 236 The acute oral toxicity of the Magtoxin formulation was found to be 9.1 mg/kg Do NOT let this chemical enter the environment. Aluminium Phosphide. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. Wear dust mask when handling large quantities. P321 Specific treatment (see ... on this label). Aluminum phosphide 20859-73-8 60 If CAS number is "proprietary", the specific chemical identity and percentage of composition has been withheld as a trade secret. Immediate medical … Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Substance information for UN 1397 - Aluminum phosphide based on the Hazardous Materials Table (Title 49 CFR 172.101) to assist in preparing a risk assessment for loading, transporting and storing hazardous materials. AlP reacts with moisture in air, water, and hydrochloric acid in the stomach to produce phosphine (PH3) gas. Other . 8F, Block C, No.3 Building, Zijin Plaza, No.701, Gudun Road, Hangzhou, Zhejiang 310030, China. /Aluminum metal and insoluble compounds/. Magnesium phosphide is a highly acute toxic substance. *Please select more than one item to compare C&L Inventory . 57% min. Pure Phosphine gas is odorless. Wear suitable protective … Fireproof. Aluminum phosphide (AlP) is an effective and cheap pesticide that is commonly used worldwide, but it is also a common cause of human poisoning and carries a high mortality rate. Aluminum phosphide is not flammable by itself. [Sax, 9th ed., p. 119]. Precautions in Storage : The product is stable under normal conditions of warehouse storage. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. (ERG, 2016). endobj Handle in accordance with good industrial hygiene and safety practice. For control of brown rats, rabbits & moles in their burrows. /Aluminum/, Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 2 mg/cu m. /Aluminum (soluble salts and alkyls, as Al)/, Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 5 mg/cu m. /Aluminum (pyro powders and welding fumes, as Al)/. /ColorSpace /DeviceGray Sweep spilled substance into covered sealable containers. Aluminum phosphide - Identification, toxicity, use, water pollution potential, ecological toxicity and regulatory information Note : See Working with the Information on this Page section below for important notes about this data. MSDS should be readily available in all workplaces storing or using the product. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Safety glasses with side-shields conforming to EN166. C&L Inventory, Biocidal active substances . Aluminium phosphide: incident management Ref: PHE publications gateway number: 2014790 PDF , 307KB , 14 pages This file may not be suitable for users of assistive technology. The main routes of exposure are through ingestion and inhalation. Search results for phosphite at Sigma-Aldrich. Protect from moisture, open flames and heat. Avoid breathing vapours, mist or gas. Contains 56% Aluminium phosphide in spherical shaped formulation. Aluminium Phosphide (Celphos-Tablet56%) Excel Crop Care Limited, India from the face and body. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Mobility in Soil:Non-mobile in the soil environment Other adverse effects:No information available 13Disposal … 139: Data from the Hazardous Materials Table Source: 49 CFR §172 (2018/07) (3) Hazard Class 4.3 Dangerous when wet materials (4) Identification number. P370+P378 In case of fire: Use ... to extinguish. Fresh air, rest. The LC 50 of hydrogen phosphide gas is about 190 ppm for a one-hour inhalation exposure. Aluminium phosphide ingested orally reacts with water and stomach acids Deleted CAS number. Formulation. Msds lib; Products; Buy offers; Encyclopedia; Suppliers; Search. /Width 236 Rated as super toxic: probable oral lethal dose is less than 5 mg/kg or less than 7 drops for a 70 kg (150 lb.) Shovel into suitable dry container. Nucl. Refer for medical attention . Keep away from acids, moisture, oxidizing agents. Chronic toxicity: Rats fed aluminium phosphide-fumigated Uses advised against Food, drug, pesticide or biocidal product use. Safety Data Sheet Talunex Page 1 of 7 Issued Jul 2015 SDS Talunex 1 Identification of the preparation and the supplying Company 1.1 Talunex 1.2 Aluminium Phosphide … %PDF-1.2 Use dry chemical or carbon dioxide. For UN1796, UN1826, UN2031 at high concentrations and for UN2032, these may act as oxidizers, also consult ERG Guide 140. �D ѐ�\0� �p.������&c6���h�@D7�` Instability 2: Readily undergoes violent chemical changes at elevated temperatures and pressures. 4. Aluminium phosphide is a highly toxic inorganic compound with the chemical formula AlP used as a wide band gap semiconductor and a fumigant. Decomposes to produce phosphine gas. Ammonium carbamate releases ammonia and carbon dioxide as shown in Equation 2. In contact with ambient air and humidity the very efficient phosphine gas is developed and released. Aluminum phosphide is a dark gray or dry, yellow, crystalline solid. Duquesne, PA 15110 . ...In contact with water, steam or alkali it slowly yields PH3 which is spontaneously flammable in air. In case of emergency: ... (PH3) present as ALUMINIUM PHOSPHIDE Each 3 g Tablet liberates 1 … Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. P403+P233 Store in a well-ventilated place. Contact with metals may evolve flammable hydrogen gas. << Signs and Symptoms of Exposure: Magnesium phosphide fumigant products react with moisture from the air, acids and many other liquids to release hydrogen phosphide (phosphine, PH 3) gas. Durch die stark exotherme Reaktion treten jedoch ungewollte Nebenreaktionen auf. P405 Store locked Aluminium Phosphide 56% tables& 85% original powder CAS NO.20859-73-8 Min.Order: 1 Metric TonFOB Price: USD $ 1.0-3.0/Metric Ton hebei yanxi chemical co., LTD who registered capital of … Aluminium phosphide is not absorbed dermally. /DecodeParms << Shipping Name: ALUMINIUM PHOSPHIDE AFI Class: 4.3 AFI ID Number: UN1397 AFI Pack Group: I AFI Label: 6.1 AFI Special Provision: A8, A19, N40 AFI Basic Pac Ref: A8.4 ----- 15. P402+P404 Store in a dry place. 1302-45-0 . (PH3) gas. scope of this MSDS, and should be performed by a competent, experienced professional. Deleted CAS number. Avoid contact with skin and eyes. IDENTIFICATION OF THE CHEMICAL PRODUCT AND COMPANY Supplier: SHANGHAI MINGDOU AGROCHEMICAL CO., LTD Address: Rm. Dark gray or dark yellow crystals. Heating produces highly toxic fumes of phosphorus oxides. Inhalation: LC50 Rat inhalation 15.5 mg/cu m/4 hr, Toxicity to daphnia and other aquatic invertebrates: no data available, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Ammonium carbamate releases ammonia and carbon dioxide which serve as a warning agent. Precautions in Storage : … SECTION I - PRODUCT INFORMATION. It reacts with moisture to give phosphine, a flammable and poisonous gas. P260 Do not breathe dust/fume/gas/mist/vapours/spray. Aluminum phosphide pesticides. Show the MSDS … Protect from moisture. ��*B`���}���}}����������k��^F�0�� �5ڧ����\q������������@����� �A��B? リン化アルミニウム(燐化アルミニウム、リンかアルミニウム、英文名称 Aluminium phosphide)は、リンとアルミニウムからなり、化学式AlPで表される無機化合物。大気中の水分と反応して毒性の強いホスフィン(リン化水素)を生じるため、殺虫剤の成分として用いられる。 P280 Wear protective gloves/protective clothing/eye protection/face protection. ALUMINIUM PHOSPHIDE; NFPA 704. Mild exposure by inhalation causes malaise (indefinite feeling of sickness), headache, ringing in the ears, fatigue, nausea and pressure in the chest which is relieved by removal to fresh air. /Name /im1 Aluminium Phosphide (Celphos-Tablet56%) Excel Crop Care Limited, India from the face and body. Flammability 4 Burns readily. The human median lethal dose for aluminum phosphide has been reported to be 20 mg/kg. �ʘ`�T�%Đ�8 aH ���d2�j���}��P�j����t����MoȜ�R��� ���A��"{����������o�������~����n8��xu�׿����/�4vC9���> ���?�������������a����~BS��! SAFETY DATA SHEET . Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. ALUMINIUM PHOSPHIDE NFPA 704 Diamond Hazard Value Description 4 4 2 W Health 4 Can be lethal. Page 2 of 6Reviewed: June 2018 Doc nr: I-MSDS-3 Aluminium Phosphide Pellets By-product Ingredient Name CAS No. Mild exposure by inhalation causes malaise (indefinite feeling of sickness), ringing in the ears, fatigue, nausea and pressure in the chest which is relieved by removal to fresh air. Proper glove removal technique ( without touching glove 's outer surface ) to avoid skin contact with water % powder... 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